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From: "David Strike" <strikinc@oz*.co*.au*>
To: "Tech Diver Mail" <techdiver@aquanaut.com>
Subject: Re: Preserving metal artifacts
Date: Thu, 26 Oct 2000 17:23:17 +1000
On Thursday, October 26, 2000 5:10 PM, Simon L Hartley wrote:

> We've (School of RSM) just come into possession of an old admiralty anchor
> that's being donated to our new marine studies centre in Coffs Harbour.
> The anchor has apparently been placed in fresh water since it's recovery
> but no preservation work has been carried out.  Can anyone offer any tips
> on preserving metal objects or point me in the direction of appropriate
> references?

Some years back some friends and I recovered an old cannon ball from
Sydney Harbour.  Although we managed to preserve it - thanks to the eforts
of Naval dockyard personnel who knew how to treat it - it inspired me to
look at ways of preserving artefacts.  I found some good information in a
book called, "Underwater Archaelogy: a nascent discipline", issued by UNESCO
in 1972.

A section by Samuel P Townsend - then of North Carolina State University -
describes Standard Conservation Procedures.

I won't quote it in it's entirety, but:

"Iron and Steel. Ferrous metals are probably the most difficult to treat.

Removal of encrustations, corrosion, and chlorides.

Mechanical cleaning:  clean objects under running water, sing wooden picks,
needles, scalpels, chisels and soft brushes. Tougher objects may be brushed
with wire brushes and tapped with ruber or plastic hammers. etc.

Chemical cleaning: Soak objects in a solution of 10-20 per cent commercil
caustic soda or 5 per cent phosphoric acid in water or, after removing
calcerous encrustations mechanically, a 50 per cent solution of managanesed
phospholene in water heated to 140 - 160 deg F.  To avoid damage remove
items about every 30 minutes, brush under running water and return to bath
as needed.

Electochemical reduction:"  (Too long to quote verbatim)

"Electrolytic reduction:  (ditto)

Thorough washing under running water:

Alternate baths in boiling and cold distilled water: This flushes out
chlorides .... from the micropores of the metal.  Each bath should last 10 -
20 minutes (longer for larger items), the volume of water being about 20
times the volume of the object.  As many as 20 to 40 baths may be required
to rinse out all removeable chlorides.  Continue baths until the silver
nitrate test indiates no chlorides in the used bath water.  Give the object
a final one-hour bath in either full-strength manganesed phospholene or
water made faintly alkaline with caustic soda.

Drying: Remove all moisture by heating the object in an oven at 212 deg.F
for 8 -48 hours.  Extreme heating of largew physically sound objects such as
anchors, cannon barrels, projectiles, inplements and tools seems to give
better results than lower heats. ........

Protective impregnation or coating:  Iron and steel must be completely
sealed from air and moisture to prevent freash corrosion. Of the six choices
listed below, waxes are probably the most widely used. ......
Impregnation with wax:  Submerge the object in molten microcrystalline wax
until bubbling ceases. (Parrafin wax, while slightly less resistant to water
vapours is also used successfully by many conservators.) Remove and wipe
excess wax from object while it is still warm. ....
Various commercially prepared clear flat laquers ... are of about equal
effectivenes.
Apply two or more coats of epoxy resin.  ..... sandpaper and then cover with
a flat enamel paint.
Zinc silicote coating:  ......
Manganesed phospholene ..... the object is simply soaked for 1 -2 hours in
the full strength chemical and dried at room temperature.
Clear plastic embedding .... especially good for artefacts that are too
delicate for mechanical cleaning or reduction, or consisting of dis-similar
materials....."

Simon!  The cannonball is obviously a lot smaller than your anchor, but
hopefully the same principles will apply.


Strike





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