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Date: Wed, 28 May 1997 18:44:20 BST
From: Steve Millard <ec96@li*.ac*.uk*>
Subject: Re: Analysing the helium in Trimix ??
To: Kent Lind <klind@al*.ne*>
cc: Techdiver <techdiver@aquanaut.com>
Hi Kent,


On Wed, 28 May 1997 08:25:39 -0700 Kent Lind wrote:



> Interesting idea.  Please post your conclusions when you sort out the
> responses. 

Sure.


 I can't find any fault in your logic but I have to wonder
> why you feel it necessary to go this route.  Are you not confident of
> your ability to mix gases using partial pressures?

Mixing for the 1st time, using an empty cylinder is no problem.  But if you
have 
a 1/2 full cylinder of trimix & want to top it up with either helium or air (or 
even O2 if you have the pressure in the bank) then the partial pressure 
calculations get a bit more suspect.  If the trimix has been stored for some 
time then there can be gas loss.  Is this just the helium of all the gas ??  I 
had a 19/45 mix go down from 250 bar to 140 bar over a 6 month lay-off period.  
An O2 analysis showed the O2 % was still 19% & so all the gas must have leaked 
as a mix.  I've heard however of helium differentially leaking.

These are the sort of problem we want to address.



  I have not mixed
> trimix so I'm just shooting in the wind here but it would seem to me
> that if you start with a helium-oxygen blend you can confirm the O2
> percentage of the mix at this stage.  Then if you add air, the change in
> O2 percentage will provide some independent confirmation of the amount
> of air (nitrogen) you have added.  Of course, this would only work if
> your initial heliox mix is less than 21  percent O2.

See above.


> 
> Secondly, Have you determined how precise you need to be in your helium
> and nitrogen percentages?  O2 seems to be the critical one.  If you are
> confident of your O2 percentage, how much difference will it make in
> your deco and MOD calculations if you change the helium/nitrogen ratio
> by a percentage point or two in either direction?

1% error in the assumed He % will make virtually no difference in the deco or 
the equivalent narcotic depth.  5% or 10% wiil start to make a signficant 
influence on both.  I just used 1% to show the accuracy that might be obtained 
by weighing to + or - 10 grams.


> 
> Finally, what will you do if your weighing method produces a result that
> is different from what you expected it would be using partial
> pressures?  Will you drain the tank and start over or will you just dive
> it anyway?  I suspect you will ultimately have to compare the precision
> of your pressure gauges to the precision of your scale and determine
> which one gives you a more precise measurement of gas percentages.
> Personally, I'd be more inclined to trust the pressure gauges as I would
> be more confident that I was measuring gas and not some other foreign
> objects on the tank.

Indeed.  It depends upon how careful one is & the sort of situation that may 
have caused an uncertainty about the He % in the first place.


     Regards, Steve M.

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*    Dr. S. G. Millard,                  * E-Mail : ec96@li*.ac*.uk*       *
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