From filling a lot of nitrox tanks, I am also inclined to believe that partial pressure mixing does not produce an instantaneous homogenous mix. I have found you can get a change of up to about 2% if you test a cylinder straight off the whip to a few hours later. Nitrox mixes seem stable after about an hour maximum in reasonably warm ambient temperatures. A good guideline is to touch the tank: if it is still warm from filling, wait a while before testing wherever possible, or allow for possible error in your dive plan. Trimixes can take significantly longer, especially if it is cold. You can really see the speed of mixing when you fill a nitrox bank with standard anti-debris tubes fitted to the valves. It can take hours for final mixing to occur. This effect can be reduced by fitting long, perforated tubes, which drop down the full length of the bank cylinders. Of course, as has been stated elsewhere, once it is mixed it stays mixed, which is just as well, or skiing and mountain climbing would probably be far less popular. Mark Caney Scubex, Cyprus Tel + 357-6-246680 (GMT + 2 hrs)
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