Mailing List Archive

Mailing List: techdiver

Banner Advert

Message Display

Date: Fri, 27 Oct 1995 10:47:02 -0600
To: techdiver@terra.net
From: chris@ab*.co* (Christopher M. Parrett)
Subject: Re: Gas Blending
>In a message dated 95-10-25 22:10:08 EDT,  DVanzandt@ao*.co* (David M.
VanZandt)
>writes:
>
>>chris.
>
>Several companies manufacture industrial scales for gravimetric mixing,
>Mettler, Setra and I believe Toledo scales.
>

Setra is who we are looking at right now.

> I presently use gravimetric mixing techniques for combustion experiments
>that I perform on NASAs KC-135 and DC-9 aircrafts and the upcoming MSL1
>spacelab mission on the shuttle(no I'm not flying this one, though I wish I
>was). We mix to K-bottles using a variety of gasses(N2, O2, SF6, CO2, H2, CH4
>etc.) to exacting specifications i.e. +/- 2% of each constituent (ex. for a
>5.00% H2, 20.00% O2, 75.00% N2,  the acceptable mixture range for H2 would be
>4.90 to 5.10%, pretty tight huh!). We confirm our mixtures using a gas
>chromatagraph calibrated over our range of interest. We use a SETRA scale
>that has an accuracy of  0.2 grams. I will have to wait until I back to
>Cleveland to get you the model number if you need it.(Presently I am working
>the STS73, USML-2 spacelab mission at Huntsville, Al , working the grave yard
>shift. So if any of this response makes any sense I will be suprised.). 
>

I Agree fully.
gravametric mixing IS THE way to go.
No ands ifs or buts!!

>Chris I think you are going about setting up your gas mixing program the
>correct way. You will probably get little in the way of help from the
>commercial gas mixing companies. We have already tried when we were doing
>partial pressure mixing and all their data is proprietary. Their gas mixing
>programs are based on empirical data collected over their years of gas mixing
>and it is still an art. If the moon is full and its raining outside and 5:00
>they know to add just a little squirt more to hit the exact mix target. We
>know this for a fact, we've watched them hit target mixtures right on the
>nose using this technique. 
>

Again, you are quite right.
They have Solid tables that they have developed over the yeas through trial
and error.
And they are not about to share them with anyone else.


>I would disagree with what you said about partial pressure mixing being
>undestood and that all you were trying to do is to take into account
>compressibility, they all go hand in hand. The first approx for partial
>pressure mixing is to use the ideal gas laws. They work good if you are at
>low pressures(tens of psi). Once you exceed about 20 to 50 psi the ideal gas
>law assumptions begin introducing errors into the final target mix. The
>second approx for pp mixing is to include compressibility into the equations.
>This gets you a little bit closer to your target mix, but in my opinion not
>close enough. The third appox is to use full blown equations of states for
>the apprpriate constituents which gets you even closer, but these are
>normally only good for a small range of pressures and are very hard to
>determine, as you have to do teh experiments for each gas and combinations to
>get anything that is useful. The fourth method is to gather empirical data
>for alot of mixes and crunch it down to workable equations and use them.
>

I did not mean to say PP was either good or fully understood.
Only that PP blening is what stores are using, for better or for worse.
There are a "few" stores that i know of that have gone to the trouble of
setting up a weight based system, but they are the exception and not the
rule. For the moment what we have is PP blending with O2 testing, and thats
pretty much it.

>We gave up on pp mixing because of its errors and went to gravimetric mixing
>because you don't have to mess with temperature, compressibility, cylinder
>size, etc. All you need to do is calculate the weights of each of the
>constituent gasses, throw a cylinder on the scale, and mix it. (If you have a
>good setup & take care of drafts, line flex etc, etc)
>
>I am really conerned with whats being mixed in the diving community. Everyone
>seems to be concerned with O2 tox, 1.4, no, 1.6, well, 1.8 or how about
>1.549. Well not to beat that point but if you do not know whats in your tank
>how can you calculate ppO2????
>

The other problem is we have no realistic means of testing anything BUT the
O2.....
Their are strong rumors that Oceanic has contracted with a medical cupply
company to use their portable gas spectrum analyser in the Phibian. If the
information I have is correct, the unit costs about $500.00 and is thermal
and humidity compensated and performs a broad spectrum analysis yeilding
N2/He/O2/CO2 etc  results!!
This would be a Hell of nice tool to have at our disposal.


>The measuring techniques I have heard discussed and the industries use of the
>Miniox makes me glad I am not diving mix yet. If and when I do I will
>definately mix my own!!! or have a decent analyzer so that I know what I
>have. Well I am digressing now so I hope this info helps you. 
>

Thanks for your kind reply.

>
>David M. VanZandt
>Senior Project Engineer
>Aerospace Design and Fabrication Inc.
>216-977-0347




Christopher M. Parrett, President, Abysmal Diving Inc.
Makers of ABYSS, Advanced Dive Planning Software.
6595 Odell Place, Suite G. Boulder CO, 80301
Ph, 303-530-7248, Fx, 303-530-2808
ftp://abysmal.com/users/abysmal http://www.emi.net/gulfstream/abyss/abyss.html

Navigate by Author: [Previous] [Next] [Author Search Index]
Navigate by Subject: [Previous] [Next] [Subject Search Index]

[Send Reply] [Send Message with New Topic]

[Search Selection] [Mailing List Home] [Home]