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Date: Tue, 24 Oct 1995 17:06:02 -0600
To: techdiver@terra.net
From: chris@ab*.co* (Christopher M. Parrett)
Subject: Gas Blending
After months of work we have a simi opperational Gas Mixing program using a
thermodynamic equation that compensates for gas compressability and
tempature rise in the cylinder during filling.

But, we are in need of some examples of "real world" fills to begin
verifying mathmatical accuracy, and tuning the equations to reflect reality
not just mathmatical predictions.

If you are pumping Nitrox, Tri-Mix, Argox, Neox, or any other blend, PLEASE,
if you would be so kind, share with me the following information.


1. Cylinder (manufacture, model, size, etc..), exp. OMS-108-steel,
Luxfer-80-aluminum.
2. Internal empty volume in Litres or Cubic Inches (if you don't know, we
can look it up for you)
3. Configuration, single or doubles.
4. Starting temp of the cylinders before filling.  (EMPTY cylinders only!,
please no tank topping yet)
5. Was the cylinder surounded by Air or Water, if Water at what Temp.
6. First gas you added.
7. Fill rate you used. (PSI or BAR /minute) or your best guess.
8. Pressure at end of each fill.
9. Temperature at end of each fill (IF possible, even subjective Warm, Hot,
Very Hot would be helpfull)
10. Time before adding next gas if any.
11. 2nd gas you added
12. fill rate (PSI or BAR /minute)
13. Pressure at end of fill  etc..
14. Final fill pressure while HOT, and then after cooling if possible as well.
15. final gas percent analysis


Right now the program is yeilding the following RAW unverified / untuned
results, which are almost certainly Wrong.

Example #1

The results of a 12.6L (Genesis 100) tank pumped to appx 239.6 ATM (3500psi)
with the following percents.

Oxygen	 21%
Nitrogen 79%

The following is the pumping order, Pressure and estimated temperature.

Gas	    AIR
Moles       99.7
Real pres   239.6atm
Temp	    74.3c
Ideal pres  238.0atm
				
Specificaly you should pump each gas to obtain a tank pressure of

Gas             AIR
Pres (atm)	239.6
Pres (psi)      3521.4
Est Temp        74.3c  165f

On colling to 20'c, the final pressure will be
202.1 ATM	2971.5 PSI

=========================
Example #2
The results of a 12.6L (Genesis 100) tank pumped to appx 239.6 ATM (3500psi)
with the following percents

Oxygen	 36%
Nitrogen 64%

The following is the pumping order, Pressure and estimated temperature.

Gas	    O2       AIR
Moles       19.1     81.5
Real pres   37.1atm  239.7
Temp	    27.6c    73.7c
Ideal pres  45.2atm  338.0atm

Specificaly you should pump each gas to obtain a tank pressure of

Gas             O2              AIR
Pres (atm)	37.1            239.7
Pres (psi)      544.7           3523.7
Est Temp        27.6c  81.7f    73.7c  164.6f

On colling to 20'c, the final pressure will be
202.6 ATM	2978.1 PSI

=========================
Example #3
The results of a 12.6L (Genesis 100) tank pumped to appx 239.6 ATM (3500psi)
with the following percents

Oxygen	  12%
Nitrogen  38%
Helium	  50%

The following is the pumping order, Pressure and estimated temperature.

Gas	    O2          He         AIR
Moles       1.9         48.8       46.9
Real pres   3.6atm      106        240
Temp	    20.6c       37.6       68.2c
Ideal pres  4.5atm      123.5      238atm

Specificaly you should pump each gas to obtain a tank pressure of

Gas             O2             He         AIR
Pres (atm)	3.6            106        240
Pres (psi)      53.5           1558       3538.7
Est Temp        20.6c  69f     37.6c  99f 68.2c  154f

On colling to 20'c, the final pressure will be
206.1 ATM	3030.1 PSI






Christopher M. Parrett, President, Abysmal Diving Inc.
Makers of ABYSS, Advanced Dive Planning Software.
6595 Odell Place, Suite G. Boulder CO, 80301
Ph, 303-530-7248, Fx, 303-530-2808
ftp://abysmal.com/users/abysmal http://www.emi.net/boynton/abyss/abyss.html

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