> When I first heard of blending nitrox using the partial pressure > method, I was told that this leads to stratification in the tank. My > experience in chemistry tells me that this is impossible, Well, I was a Doubter, too, until I actually *saw* it happen. The particular incident occurred with a tank that I mixed *myself* (I am an IANTD Nitrox Instructor and Gas Blender). The tank was a Genesis 80, which started out with a couple hundred PSI of a standard mix (32 or 36, can't remember which). At any rate, I did the math and added however much pure O2 I needed for the mix I wanted, topped with air to the tank's rated pressure (3500 PSI), and then checked the mix with a Mini-Ox. To my surprise, the FO2 read significantly lower than I expected, so I checked the FO2 with another analyzer - same result. I then re-did the math, but all the numbers checked out. The owner of the dive shop happened to be standing there while I was doing all this, and suggested that the mix might have stratified, and said I should roll the tank back and forth for a few minutes to see if the FO2 changed. I was skeptical, but decided to try it anyway, rather than blow a whole fill and have to start over. Well, I rolled the tank for a few minutes, re-checked with the Mini-Ox, and sure enough, the FO2 had gone up by a few percentage points. After a few more minutes of rolling, the FO2 had risen to what my "target" was, after which it leveled off (note that I did not adjust the calibration on the Mini-Ox at any point). I have only observed this phenomenon just the one time with that one tank, but since I could not come up with any other explanation for what I observed, then I assume it must have been the result of stratification. So now I am a Believer. Any Doubters out there care to shoot holes in what I saw? -JimG
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