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To: techdiver@opal.com
Subject: cavitation
From: egray@me*.ad*.ed*.au*
Date: Tue May 10 10:27:29 1994
Prime rat suggested that I explain cavitation.  Please also 
refer to Roger's post which is informative.

Cavitation in the present context is the formation of a gas
phase (eg. a bubble) in liquid by transient supersaturation of the 
liquid due to a sudden reduction in the local ambient pressure.  
Remember that supersaturation exists if the gas and vapour pressure 
in a liquid exceeds ambient pressure.  Such reductions in ambient 
pressure occur in a syringe when the plunger is withdrawn against 
a closed end as the volume is increased, another situation is when 
two closely opposed surfaces in a fluid are rapidly drawn apart, the 
flow of liquid into the resulting space is resisted by the viscosity 
of the liquid creating a transient localized reduction of ambient 
pressure.  An example of the latter situation are the articular 
surfaces of a joint in the synovial capsule (eg. a knuckle).  The 
resultant pressure reductions can be many hundreds of atmospheres. 
During such brief periods of negative pressure the solution is 
supersaturated and bubbles can form.  The first event is the formation 
of a bubble of water vapour, vapourous cavitation.  Since in the 
syringe and knuckle contain aqueous solutions there is plenty of water 
to form vapour from so a large gas phase can occur.  The water is 
essentially boiling, a phenomena that is based on increasing water 
vapour pressure above ambient pressure (by raising the water temperature
or lowering ambient pressure).  This vapourous bubble will be 
extinguished as soon as the pressure increases, this is apparently 
the popping sound in a knuckle.  Secondary to vapourous cavitation, 
gaseous cavitation may occur if gas dissolved in the liquid comes out 
of solution during the brief period of suppersaturation.  Physics
is stacked against the formation of small (there is less gas 
available than water vapour) bubbles because surface tension 
tends to collapse them, but the gas can easily evolve into the vapourous 
bubble. Under the appropriate conditions (another story), the gaseous 
phase may persist after the vapourous phase is extinguished.  Some 
people call this form of cavitation tribonucleation.  There are many 
other forms of cavitation, some already mentioned in other posts.

I doubt these bubbles in the joints cause any DCI in situ, if you 
have ever seen an arthroscopy the synovial fluid is full of bubbles 
introduced during the procedure and these patients do not develop 
DCI.  I suppose that theoretically the bubbles may track along the 
articular surfaces to somewhere that causes DCI but I can't think 
where.  The point about cavitation is that it is evoked to 
explain the formation of gas nuclei from which bubbles can grow 
during decompression since the formation of gas nuclei by the
`supersaturations' theoretically produced by diving is impossible.  
Cavitation may occur elsewhere in the body.
Although the literature is divide, it seems that dead animals don't
bubble as much as live ones.

David Doolette
ddoolett@me*.ad*.ed*.au*

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